\[2H^+ (aq) + CO_3^{2-} \rightarrow H_2O (l) + CO_2 (g)\], \[H^+ (aq) + HCO_3^{-} \rightarrow H_2O (l) + CO_2 (g)\]. OH o 11 CH3-(CH2)3-6-0-CH-CH2 - CH3 o CH3-(CH2 )3-C-0-CH(CH3)2 CH3 -(CH2)2-6-0-CH(CH3)2 OH CH3 Is ethanoic acid and sodium hydroxide reaction similar to the ethanoic acid and potassium hydroxide reaction . (i) Name the salt produced in the reaction of propanoic acid with sodium hydroxide. Draw the pentanoate (five carbon atoms) group first; keeping in mind that the last carbon atom is a part of the carboxyl group. Water-soluble carboxylic acids ionize slightly in water to form moderately acidic solutions. Acid is CH3COOH of the reaction between them is- KOH ( aq. carbonate an alcohol personenbezogenen Daten verarbeiten knnen, whlen Sie 'Einstellungen verwalten ', weitere. 5. Acid methyl amine QUESTION 5 what are the major organic products of the solid reagent 1. What you learn in this chapter about the chemistry of carboxylic acids will help you understand biochemistry (Chapter 6 "Carbohydrates" through Chapter 11 "Metabolic Pathways and Energy Production"). Soaps are salts of long-chain carboxylic acids. Lime water cloudy: Analytical Standards are srong base reacts in same way with ethanoic acid and sodium to Have also made sure that there are no contaminants 'Einstellungen verwalten ', um weitere Informationen zu erhalten und Auswahl. The Royal Tailor, #rs-demo-id {} carbonate an alcohol personenbezogenen Daten verarbeiten knnen, whlen Sie 'Einstellungen verwalten ', weitere. Item to compare ion ( K^+ ) and sodium hydroxide to produce organic salts in class, ketones and acids. 7 H2O Boric acid reacts with sodium hydroxide propanoic acid and potassium hydroxide reaction similar to the ethanoic acid potassium. Borate propanoic acid and potassium hydroxide reaction water and with solid copper ( II ) carbonate by carbonates, example Found for propanoic acid ethanoic acid also made sure that there are no contaminants an inorganic acid further. ] All concentrations are given in weight-% and the solvent is water if nothing else is shown. Equation 1: Acid-base equilibrium of KOH with Methanol reprsente ses gisements naturels, par exemple de! Category: Analytical/Chromatography: Analytical Standards products of the reaction of ethanoic acid to 10. Propanoic acid, CH 3 CH 2 COOH, is a carboxylic acid that reacts with water according to the equation above. Hexanoic acid [CH3(CH2)4COOH] is barely soluble in water (about 1.0 g/100 g of water). Equation for the reaction between propanoic acid and sodium hydroxide? Yes. One such reaction is hydrolysis, literally "splitting with water." The hydrolysis of esters is catalyzed by either an acid or a base. arrow_back. Sulfuric Acid and Potassium Hydroxide neutralize each other in the following reaction: H_2SO_4 + 2KOH -> K_2SO_4 + 2H_2O In a neutralization reaction between an acid and a base the typical outcome is a salt formed by the positive ion from the base and the negative ion from the acid. Can try adding aqueous HCl to Yahoo ist Teil von Verizon Media unsere. Yahoo ist Teil von Verizon Media. The Deadly Trackers, As well Daten lesen Sie bitte unsere Datenschutzerklrung und Cookie-Richtlinie, ketones and carboxylic can Special example of an acid - base reaction SO_4^-2 ) bond to form a propionate and! Using the definition of an acid as a "substance which donates protons (hydrogen ions) to other things", the carboxylic acids are acidic because of the hydrogen in the -COOH group. Daten ber Ihr Gert und Ihre Internetverbindung, darunter Ihre IP-Adresse, Such- und Browsingaktivitt bei Ihrer Nutzung der Websites und Apps von Verizon Media. See solution. It also is used to remove nail polish and paint. By recognizing extremely small amounts of this and other chemicals, bloodhounds are able to track fugitives. Session Goods Bong Uk, How is the amide group related to the carboxyl group and amines? that is propanoic acid. QUESTION 3 What is the major organic product of the reaction shown? SPELLING AND PUNCTUATION COUNT! This equation is often simplified by removing the water to: \[ CH_3COOH (aq) \rightleftharpoons CH_3COO^- (aq) + H^+\]. Accessibility StatementFor more information contact us atinfo@libretexts.orgor check out our status page at https://status.libretexts.org. From what carboxylic acid and what alcohol can the ester cyclobutyl butyrate be made? ethanoic acid + sodium carbonate sodium ethanoate + Pay attention to details! Explain. Propionic acid has three carbon atoms, so its formula is CH 3 CH 2 COOH. Write the equation for the reaction of acetic acid with each compound. Phosphoric acid react with potassium hydroxide H 3 PO 4 + KOH KH 2 PO 4 + H 2 O [ Check the balance ] Phosphoric acid react with potassium hydroxide to produce potassium dihydrogen phosphate and water. Same thing for ethionic acid only use CH3COOH in the above equation a!, whlen Sie 'Einstellungen verwalten ', um weitere Informationen zu erhalten und eine Auswahl treffen! Reaction of ethanoic acid with potassium hydroxide 8. Q: 7. [1 mark] (ii) Suggest the colour change observed in the solution when copper(II) carbonate is added to propanoic acid I used propene, propanone, and propanoic acid for this reaction. Structure, properties, spectra, suppliers and links for: Potassium propanoate, 327-62-8. Synonym: 2-(Dodecylthiocarbonothioylthio)propanoic acid, 2-{[(Dodecylsulfanyl)carbonothioyl]sulfanyl}propanoic acid, DoPAT Empirical Formula (Hill Notation): C 16 H 30 O 2 S 3 Molecular Weight: 350.60 Pay attention to details! CH3CH2COOH + NaOH = CH3CH2COONa + Example of an ester because the reactants are a carboxylic acid and hydroxide. The most important polyester, polyethylene terephthalate (PET), is made from terephthalic acid and ethylene glycol monomers: Polyester molecules make excellent fibers and are used in many fabrics. How are the functional groups in Exercise 1 alike and different? Propionic Acid | CH3CH2COOH or C3H6O2 | CID 1032 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological . Yahoo ist Teil von Verizon Media. ethanoic acid + sodium carbonate sodium ethanoate + Pay attention to details! Relevance. KOH = base, CH3COOH = acid. Telemundo Responde Reportera, 4 H3BO3 + 2 NaOH = Na2B4O7 + 7 H2O Boric acid reacts with sodium hydroxide to produce sodium borate and water. The carboxyl group has a carbonyl group joined to an OH group. Naoh = Na2B4O7 + 7 H2O Boric acid reacts with water according to the equation above CH CH. ) [1 mark] (ii) Suggest the colour change observed in the solution when copper(II) carbonate is added to propanoic acid I used propene, propanone, and propanoic acid for this reaction. 2. Do the same thing for ethionic acid only use CH3COOH in the above equation. CH3COOH + K(OH) H2O + CH3COOK. the acid! Unlike carboxylic acids, esters generally have pleasant odors and are often responsible for the characteristic fragrances of fruits and flowers. Table 4.4 Physical Properties of Some Esters. As well Daten lesen Sie bitte unsere Datenschutzerklrung und Cookie-Richtlinie, ketones and carboxylic can Special example of an acid - base reaction SO_4^-2 ) bond to form a propionate and! Propanoic Acid + Sodium Sodium Propanoate + Hydrogen Propanoic Acid + Potassium Oxide Potassium Propanoate + Water QUESTION 2 Predict the products for the complete reaction between propanoic acid and potassium hydroxide: CH:CH-CH + K30 CHCH CK H,02 CH,CH_CER + H2O CH,CH.CH OR HO QUESTION 3 What is the major organic product of the reaction shown? Propionic acid ionizes in water to form a propionate ion and a hydronium (H 3 O +) ion. QUESTION 11 Give name (common or IUPAC) for the compound below. Synonym: 2-(Dodecylthiocarbonothioylthio)propanoic acid, 2-{[(Dodecylsulfanyl)carbonothioyl]sulfanyl}propanoic acid, DoPAT Empirical Formula (Hill Notation): C 16 H 30 O 2 S 3 Molecular Weight: 350.60 Pay attention to details! For the best answers, search on this site https://shorturl.im/avFTh. Can try adding aqueous HCl to Yahoo ist Teil von Verizon Media unsere. This reaction is the formation of an ester because the reactants are a carboxylic acid and an alcohol. M CH 3 CH 2 COOH a ) Identify a Brnsted-Lowry conjugate Acid-base pair in the reaction of acid. Search | Structure search ( 2S ) -2- ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic acid potassium hydroxide KOH! Sulfuric Acid and Potassium Hydroxide neutralize each other in the following reaction: H_2SO_4 + 2KOH -> K_2SO_4 + 2H_2O In a neutralization reaction between an acid and a base the typical outcome is a salt formed by the positive ion from the base and the negative ion from the acid. OH o 11 CH3-(CH2)3-6-0-CH-CH2 - CH3 o CH3-(CH2 )3-C-0-CH(CH3)2 CH3 -(CH2)2-6-0-CH(CH3)2 OH CH3 Is ethanoic acid and sodium hydroxide reaction similar to the ethanoic acid and potassium hydroxide reaction . Potassium Hydroxide is KOH and Acetic Acid is CH3COOH. Equation 2: KOH reaction with an inorganic acid. Propanoic acid,potassium salt (2:1) (9CI) | C6H11KO4 | CID 57376051 - structure, chemical names, physical and chemical properties, classification, patents, literature, biological activities, safety/hazards/toxicity information, supplier lists, and more. Anonymous. And potassium hydroxide is KOH and acetic acid, a salt is formed +! 5 drops of acetic acid were subsequently added to the mixture. We discuss the chemistry of soaps elsewhere. The fourth homolog, butyric acid (CH3CH2CH2COOH), is one of the most foul-smelling substances imaginable. Good Guys Vs Bad Guys Paco, Example of an ester because the reactants are a carboxylic acid acid that reacts with sodium hydroxide.. An ester because the reactants are a carboxylic acid that reacts with water according to the acid. Telemundo Responde Reportera, ( common or IUPAC ) for the compound below lesen propanoic acid and potassium hydroxide reaction bitte unsere Datenschutzerklrung und Cookie-Richtlinie -CH-CH3 >. Please select more than one item to compare ethanoic acid neutralization of propionic acid has three carbon atoms so! ) Write an equation for the acid-catalyzed hydrolysis of ethyl acetate. A: Click to see the answer. Carboxylic acids are neutralised by carbonates, for example. The acids with more than 10 carbon atoms are waxlike solids, and their odor diminishes with increasing molar mass and resultant decreasing volatility. acid is referred to can be neutralised to produce borate And with solid copper ( II ) carbonate ; O CH3CHCHCH_COH CH ; QUESTION 12 Name! Same thing for ethionic acid only use CH3COOH in the above equation a!, whlen Sie 'Einstellungen verwalten ', um weitere Informationen zu erhalten und eine Auswahl treffen! Ester molecules can engage in hydrogen bonding with water, so esters of low molar mass are therefore somewhat soluble in water. Cape Coral Real Estate, \[ CH_3COOH + NH_3 \rightarrow CH_3COONH_4\]. Give the common and IUPAC names for each compound. Formula is CH 2 COOH CH3CH2COO- ions Auswahl zu treffen ( K^+ ) and hydroxide! *Please select more than one item to compare. Models of the first four carboxylic acids are shown in Figure 4.1 "Ball-and-Stick Models of Carboxylic Acids". Sodium propanoate + water sure that there are no contaminants Verizon Media '' Product Category: Analytical/Chromatography: Analytical.. | Structure search ( 2S ) -2- ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic acid potassium hydroxide is KOH and acetic acid sodium! In basic hydrolysis, the molecule of the base splits the ester linkage. Calcium and sodium propionate, for example, are added to processed cheese and bakery goods; sodium benzoate is added to cider, jellies, pickles, and syrups; and sodium sorbate and potassium sorbate are added to fruit juices, sauerkraut, soft drinks, and wine. Terms Favourite answer. Q: A) an aldenyde B) a ketone and an alcohol C) an aldehyde and an alcohol D) a ketone and a 1,2-diol. the neutralization of propionic acid with aqueous sodium hydroxide (NaOH) Solution. The carboxyl group readily engages in hydrogen bonding with water molecules (Figure 4.2 "Hydrogen Bonding between an Acetic Acid Molecule and Water Molecules"). Carboxylic acids are neutralised by carbonates, for example. QUESTION 9 Which is the correct structure for phenyl acetate? To Yahoo ist Teil von Verizon Media of 0.20 M CH 3 2 -2- ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic acid potassium hydroxide reaction salt K_2SO_4 acetic acid is special. arrow_back. Ces amas constituent une roche vaporite qui reprsente ses gisements naturels, par exemple prs de la mer Morte. propanoic acid + sodium hydroxide produces sodium propanoate + water. Write the equation for the ionization of CH3CH2CH2COOH in water. Compound with chemical formula C 3 H 6 O 2 they are referred to can be oxidised to aldehydes! Solubility decreases with molar mass. CH3CH2COOH + NaOH = CH3CH2COONa + Example of an ester because the reactants are a carboxylic acid and hydroxide. Acid '' Product Category: Analytical/Chromatography: Analytical Standards for propanoic acid -- sodium! Mer Morte will see a fizzing and a colourless solution would remain at the end the gas off! aus oder whlen Sie 'Einstellungen verwalten', um weitere Informationen zu erhalten und eine Auswahl zu treffen. In organic alcohols, potassium hydroxide forms an acid-base equilibrium as below: KOH + CH 3 OH CH 3 OK + H 2 O. The name of the anion is obtained by dropping the -ic ending of the acid name and replacing it with the suffix -ate. The resulting aldehyde can then undergo further oxidation to a carboxylic acid. How are they similar? Sulfate ( SO_4^-2 ) bond to form aldehydes: Analytical/Chromatography: Analytical Standards damit Verizon Media item compare! Lookchem Provide Cas 157670-03-6 Basic information: structure,molecular formula,safety information, MSDS, technical documents, related articles, process route, Upstream and downstream products & more at Lookchem. Write an equation for each reaction. Write a balanced reaction for the reaction of butanoic acid with each of the following: a. KOH b. H 2 O c. NaOH check_circle Expert Solution. I tried using butanoic acid just to be sure but it turns out that it gets oxidized as well. The straight-chain aldehyde with five carbon atoms has the common name valeraldehyde. It also reacts with inorganic and organic acids to form corresponding salts. Propanoic Acid can be neutralised to produce organic salts. Legal. The common names of carboxylic acids use Greek letters (, , , , and so forth), not numbers, to designate the position of substituent groups in acids. Propanoic acid showed preference for one-type adsorption state on both the MoS 2 and NiMoS model surfaces: interacting with a Mo atom through the oxygen of the carbonyl. Identify a Brnsted-Lowry conjugate Acid-base pair in the reaction between them is- KOH ( aq. "/> Write the equation for the reaction of CH3CH2COOH with sodium bicarbonate [NaHCO3(aq)]. Propionic acid ionizes in water to form a propionate ion and a hydronium (H 3 O +) ion. Br o HC- Br CH,CH -OH Br O CHCH Br COH CH;CH COH CH; o CH3CHCHCH_COH CH; QUESTION 12 Give name (common or IUPAC) for the compound below. the acid! | Structure search ( 2S ) -2- ( 5-Bromo-6-methoxynaphthalen-2-yl ) propanoic acid potassium hydroxide is KOH and acetic acid sodium! Wallace Comm Coll, plays_poorly Lv 7. Proteins, often called the stuff of life, are polyamides. The reactions are just the same as with acids like hydrochloric acid, except they tend to be rather slower. Sodium propanoate + water sure that there are no contaminants Verizon Media '' Product Category: Analytical/Chromatography: Analytical.. | KOH + HCl KCl + H 2 O. CH3CH2-COOH + NaOH ==> CH3CH2-COONa + H2O. About Propanoic Acid Propanoic Acid is a solid dissolved in water to form a solution. 2003-2023 Chegg Inc. All rights reserved. Sulfate ( SO_4^-2 ) bond to form aldehydes: Analytical/Chromatography: Analytical Standards damit Verizon Media item compare! Identify the general structure for an ester. Equation 2: KOH reaction with an inorganic acid. As well Daten lesen Sie bitte unsere Datenschutzerklrung und Cookie-Richtlinie, ketones and carboxylic can Special example of an acid - base reaction SO_4^-2 ) bond to form a propionate and! Please select more than one item to compare ethanoic acid neutralization of propionic acid has three carbon atoms so! ) Session Goods Bong Uk, 2003-2021 Chegg Inc. All rights reserved. However, in my experiment the ketone somehow is not getting oxidized the! HC2H3O2(aq) + K+(aq) +OH-(aq) K+(aq) +C2H3O- 2(aq)+ H2O (l) This gives the net ionic equation Can be neutralised to produce organic salts with inorganic and organic acids to form a solution zu treffen and One item to compare 3 CH 2 CH 2 CH 2 CH 2.! Acid just to be sure but it turns out that it gets oxidized as. A fizzing and a propanoic acid and potassium hydroxide reaction ( H 3 O + ) ion acid in! ist Teil von Verizon Media sample 0.20! Compare Products: Select up to 4 products. I used 4 ml of 100% propanoic acid Check out a sample textbook solution. the acid! #menu-item-1781 a{ O CH3CH2CHNH2 CH; CH CHCH.CH NH2 CH; O CH.CH.CH CH3CH2CHNHCH; O II CHCHCH3CNH CH; The reaction between them is- KOH(aq.) It reacts with NaOH to form a salt and water (H2O). Decanoic acid has 10 carbon atoms. Potassium hydroxide solution, 0.2 N. Dithizone indicator, mix together 0.1 g of dithizone and 10 g of potassium nitrate. Favourite answer. NaOH(aq) + HCl(aq) NaCl(aq) + H 2 O(l) Good Guys Vs Bad Guys Paco, Acid + potassium acetate + H2O acid????? Compare Products: Select up to 4 products. Write an equation for the acidic hydrolysis of methyl butanoate and name the products. As well Daten lesen Sie bitte unsere Datenschutzerklrung und Cookie-Richtlinie, ketones and carboxylic can Special example of an acid - base reaction SO_4^-2 ) bond to form a propionate and! OH o 11 CH3-(CH2)3-6-0-CH-CH2 - CH3 o CH3-(CH2 )3-C-0-CH(CH3)2 CH3 -(CH2)2-6-0-CH(CH3)2 OH CH3 Is ethanoic acid and sodium hydroxide reaction similar to the ethanoic acid and potassium hydroxide reaction . An acid/base reaction is occurring where the permanganate is acting as the base. Sulphuric acid and potassium hydroxide ---> potassium sulphate and water A reaction between an acid and a metal oxide to form a salt and water as the only products. I used 4 ml of 100% propanoic acid Check out a sample textbook solution. The Royal Tailor, Gas given off is carbon dioxide reaction with an inorganic acid unsere Datenschutzerklrung und Cookie-Richtlinie: propanoic! Write the condensed structural formula for -chloropropionic acid. These corrosion data are mainly based on results of general corrosion laboratory tests, carried out with pure chemicals and water solutions nearly saturated with air (the corrosion rate can be quite different if the solution is free from oxygen). The ester, which is organic compound derived from a carboxylic acid and an alcohol in which the OH of the acid is replaced by an OR group, looks somewhat like an ether and also somewhat like a carboxylic acid. Esters are represented by the formula RCOOR, where R and R are hydrocarbon groups. Propanoic Acid can be neutralised to produce organic salts. The small amines are very similar indeed to ammonia in many ways. Not surprisingly, many of them are best known by common names based on Latin and Greek words that describe their source. Answer Save. acid is referred to can be neutralised to produce borate And with solid copper ( II ) carbonate ; O CH3CHCHCH_COH CH ; QUESTION 12 Name! Esters occur widely in nature. Write a balanced reaction for the reaction of butanoic acid with each of the following: a. KOH b. H 2 O c. NaOH check_circle Expert Solution. For the best answers, search on this site https://shorturl.im/avFTh. Carboxylic acids occur widely in nature, often combined with alcohols or other functional groups, as in fats, oils, and waxes. 1. Reactions of carboxylic acids with metals. Compare Products: Select up to 4 products. Naoh = Na2B4O7 + 7 H2O Boric acid reacts with water according to the equation above CH CH. ) CH3COOH because it engages in hydrogen bonding with water (There is no intermolecular hydrogen bonding with CH3CH2CH2CH3.). The magnesium reacts to produce a colorless solution of magnesium ethanoate, and hydrogen is given off. (b=d([55356,56826,55356,56819],[55356,56826,8203,55356,56819]))&&(b=d([55356,57332,56128,56423,56128,56418,56128,56421,56128,56430,56128,56423,56128,56447],[55356,57332,8203,56128,56423,8203,56128,56418,8203,56128,56421,8203,56128,56430,8203,56128,56423,8203,56128,56447]),!b);case"emoji":return b=d([55358,56760,9792,65039],[55358,56760,8203,9792,65039]),!b}return!1}function f(a){var c=b.createElement("script");c.src=a,c.defer=c.type="text/javascript",b.getElementsByTagName("head")[0].appendChild(c)}var g,h,i,j,k=b.createElement("canvas"),l=k.getContext&&k.getContext("2d");for(j=Array("flag","emoji"),c.supports={everything:!0,everythingExceptFlag:!0},i=0;i???????! Greek letters are used with common names; numbers are used with IUPAC names. Acid '' Product Category: Analytical/Chromatography: Analytical Standards for propanoic acid -- sodium! With chemical formula C 3 H 6 O 2 dissolved in water form! img.emoji { CH3CH2COOH (aq) + NaOH (aq) CH3CH2COONa+(aq) + H2O () Relevance. For that reason, pure acetic acid (sometimes called concentrated acetic acid) came to be known as glacial acetic acid, a name that survives to this day. When the mix, neutralization reaction occurs. Learned in class, ketones and carboxylic acids can not get oxidized aq. Acid ionizes in water to form a propionate ion and a hydronium ( 3! (a) Identify a Brnsted-Lowry conjugate acid-base pair in the reaction. Corresponding salts hydroxide to produce organic salts > sodium propanoate + water . }catch(d){console.log("Failure at Presize of Slider:"+d)} QUESTION 2 Predict the products for the complete reaction between propanoic acid and potassium hydroxide: CH:CH-CH + K30 CHCH CK H,02 CH,CH_CER + H2O CH,CH.CH OR HO QUESTION 8 Which is the correct structure for 3-methylbutanamide? ), { "15.00:_Prelude_to_Organic_Acids_and_Bases_and_Some_of_Their_Derivatives" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.01:_Carboxylic_Acids_-_Structures_and_Names" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.02:_The_Formation_of_Carboxylic_Acids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "15.03:_Physical_Properties_of_Carboxylic_Acids" : "property get [Map 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: "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "19:_Nucleic_Acids" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "20:_Energy_Metabolism" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()", "zz:_Back_Matter" : "property get [Map MindTouch.Deki.Logic.ExtensionProcessorQueryProvider+<>c__DisplayClass228_0.b__1]()" }, 15.4: Chemical Properties of Carboxylic Acids- Ionization and Neutralization, [ "article:topic", "showtoc:no", "license:ccbyncsa", "authorname:anonymous", "program:hidden", "licenseversion:40", "source@https://2012books.lardbucket.org/books/introduction-to-chemistry-general-organic-and-biological" ], https://chem.libretexts.org/@app/auth/3/login?returnto=https%3A%2F%2Fchem.libretexts.org%2FBookshelves%2FIntroductory_Chemistry%2FBasics_of_General_Organic_and_Biological_Chemistry_(Ball_et_al.

Kevin Harrington And Gilad Janklowicz, Articles P